Preparation of allyltin reagents grafted on solid support: clean and easily recyclable reagents for allylation of aldehydes.
نویسندگان
چکیده
The preparation of polymer-supported allyltin reagents was shown to be possible for both unfunctionalized and functionalized allyl units. These reagents were treated with aldehydes in the presence of cerium(III) or indium(III) salts to afford high yields of homoallylic alcohols, practically uncontaminated with organotin residues (less than 5 ppm). Some mechanism aspects are briefly discussed and the potential for regeneration and reuse of these supported reagents is pointed out.
منابع مشابه
Clean and direct synthesis of alpha,alpha'-bithiophenes and bipyrroles by metal-free oxidative coupling using recyclable hypervalent iodine(III) reagents.
The facile and clean oxidative biaryl coupling reaction of thiophenes and pyrroles has been achieved using the recyclable hypervalent iodine(III) reagents having adamantane or methane structures. These iodine(III) reagents could be recovered from the reaction mixtures by a simple solid-liquid separation, i.e., filtration.
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ورودعنوان ژورنال:
- Chemistry
دوره 12 26 شماره
صفحات -
تاریخ انتشار 2006